Phosphorus incorporation for n-type doping of diamond with (100) and related surface orientation

ABSTRACT

Apparatuses and methods are provided for manufacturing diamond electronic devices. The method includes at least one of the following acts: positioning a substrate in a plasma enhanced chemical vapor deposition (PECVD) reactor; controlling temperature of the substrate by manipulating microwave power, chamber pressure, and gas flow rates of the PECVD reactor; and growing phosphorus doped diamond layer on the substrate using a pulsed deposition comprising a growth cycle and a cooling cycle.

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH

This disclosure was made with government support under DE-AR0000453 awarded by the Advanced Research Projects Agency-Energy (ARAPA-E). The government has certain rights in the disclosure.

CROSS-REFERENCES TO RELATED APPLICATIONS

Not Applicable.

BACKGROUND

Diamond electronics can provide significant advances in high power and high frequency electronics, radiation detectors for medical and military applications, and UV optoelectronics due to exceptional material properties like large bandgap energy (5.5 eV), the breakdown electric field (10 MV/cm), the carrier mobilities (˜2200 and ˜1600 cm2/Vs for electrons and holes resp.), the thermal conductivity (10-20 W/cmK), the low dielectric constant (5.5), and the excellent resistance to radiation. Requisite for diamond electronics is the preparation of n-type and p-type material, the building blocks for discrete semiconductors.

While p-type diamond can be readily obtained through boron doping, n-type doping is still challenging especially for (100) oriented diamond surfaces. Various approaches for increased doping efficiency have focused on off-axis surfaces where the (100) surface is polished at an angle to establish a boundary that has been shown to promote the incorporation of phosphorus impurities. However, these approaches have suffered from repeatability and reliability issues, and most electronically suitable n-type diamond devices are still prepared from (111) wafers which limits the device properties and has a disadvantage in cost and maximum wafer size.

Thus, there is a need for new methods and devices for increasing doping efficiency in diamond surfaces.

SUMMARY

According to a first aspect, a method is provided for manufacturing diamond electronic devices. The method includes at least one of the following acts: positioning a substrate in a plasma enhanced chemical vapor deposition (PECVD) reactor; controlling temperature of the substrate by manipulating microwave power, chamber pressure, and gas flow rates of the PECVD reactor; and growing phosphorus doped diamond layer on the substrate using a pulsed deposition comprising a growth cycle and a cooling cycle.

According to a second aspect, a method is provided for manufacturing diamond electronic devices. The method may be implemented in a PECVD reactor including: a base and a sample stage holder disposed on the base. The sample stage holder includes a sample holder. The method further includes at least one of the following acts: adjusting a thermal interface between the base and the sample stage holder; positioning a substrate in the sample holder in the PECVD reactor; and growing phosphorus doped diamond layer on the substrate using a pulsed deposition.

It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a homoepitaxial n-i-p diode structure according to the disclosure.

FIG. 2a illustrates an apparatus according to the disclosure.

FIG. 2b illustrates the apparatus of FIG. 2 a.

FIG. 2c illustrates the apparatus of FIG. 2 a.

FIG. 3a illustrates temperature changes over time according to the disclosure.

FIG. 3b illustrates averaged and simulated temperature changes over time according to the disclosure.

FIG. 4 illustrates P concentration over depth according to the disclosure.

FIG. 5a illustrates a method according to a first aspect of the disclosure.

FIG. 5b illustrates additional acts in the method of FIG. 5a according to the disclosure.

FIG. 5c illustrates additional acts in the method of FIG. 5a according to the disclosure.

FIG. 6a illustrates an example method according to a second aspect of the disclosure.

FIG. 6b illustrates additional acts in the method of FIG. 6a according to the disclosure.

FIG. 6c illustrates additional acts in the method of FIG. 6a according to the disclosure.

FIG. 7a illustrates an outline of a sample holder according to the disclosure.

FIG. 7b illustrates a detailed view of the sample holder of FIG. 7a according to the disclosure.

FIG. 7c illustrates a sample holder with elevated diamond substrate positioning according to the disclosure.

FIG. 8a illustrates flow channel distribution on a sample holder according to the disclosure.

FIG. 9a illustrates a sample stage with a single sample holder according to the disclosure.

FIG. 9b illustrates a sample stage with multiple sample holders according to the disclosure.

FIG. 10 illustrates a reactor according to the disclosure.

DETAILED DESCRIPTION OF THE DISCLOSURE

Before the present disclosure is described in further detail, it is to be understood that the disclosure is not limited to the particular embodiments described. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. The scope of the present disclosure will be limited only by the claims.

As used herein, the singular forms “a”, “an”, and “the” include plural embodiments unless the context clearly dictates otherwise.

Specific structures, devices, and methods relating to manufacturing of diamond electronic devices have been disclosed. It should be apparent to those skilled in the art that many additional modifications beside those already described are possible without departing from the inventive concepts. In interpreting this disclosure, all terms should be interpreted in the broadest possible manner consistent with the context. Variations of the term “comprising” should be interpreted as referring to elements, components, or steps in a non-exclusive manner, so the referenced elements, components, or steps may be combined with other elements, components, or steps that are not expressly referenced. Embodiments referenced as “comprising” certain elements are also contemplated as “consisting essentially of” and “consisting of” those elements. If a series of numerical ranges are recited, this disclosure contemplates combinations of the lower and upper bounds of those ranges that are not explicitly recited. For example, if a range between 1 and 10 or between 2 and 9 is recited, this disclosure also contemplates a range between 1 and 9 or between 2 and 10.

For example, manufacturing of diamond electronic devices based on (100) oriented substrates may be preferred due to its electronic properties and more economical fabrication. Obtaining n-type and p-type electronic character through impurity doping is necessary for diamond electronics and optoelectronics. Implantation doping of diamond has shown limited success and incorporation of dopant impurities (B, P, N) during epitaxial layer growth is the primary approach for fabrication of diamond electronic device structures. For diamond, the preparation of n-type semiconducting (100) material still presents a challenge, while (111) oriented surfaces readily accept phosphorus as donor states in the lattice. The disclosure provides a method and apparatus for significant phosphorus incorporation in epitaxial diamond layers grown on (100) oriented substrates through the use of a pulsed deposition technique.

FIG. 1 illustrates a homoepitaxial quasi-vertical n-i-p diode structure according to the disclosure. The homoepitaxial quasi-vertical n-i-p diode structure 100 includes a substrate 110, which may be a substrate with an optical grade having a transmission greater than 70%. For example, the substrate may be a type IIa plate with a dimension of 3 mm by 3 mm. For true vertical devices the substrate may be a boron doped type IIb plate. The layer 120 may be a film doped boron for p-type material and the layer 140 may be a film doped with phosphorus for n-type material. The layer 130 between layers 120 and 140 may be an intrinsic or lightly doped interface layer. The n-i-p diode structure 100 may further include n+ layer 150 deposited on the layer 140. For example, the layer 120 may be a p-type layer doped with Boron. The layer 120 may have a thickness of about 9.95 um.

The n-i-p diode structure 100 may further include contact layers 122 and 124 deposited on the layer 120. The contact layers 122 and 124 may include Ti/Pt/Au with respective thicknesses of about 50 nm/50 nm/150 nm. The n-i-p diode structure 100 may further include a contact layer 160 deposited on the n+ layer 150. The contact layer 160 may include Ti/Pt/Au/Ni with respective thicknesses of about 50 nm/50 nm/150 nm/50 nm.

To grow a phosphorus doped diamond layer on the substrate, a CVD reactor may be used to heat the substrate using plasma. The CVD reactor may include a phosphorus source including 200 ppm trimethylphosphine/hydrogen gas mixture. The CVD reactor may include a fluid-cooled sample stage that exploits plasma focusing. The CVD reactor may use a pyrometer and reflectivity change to monitor temperature and film thickness.

FIG. 2a illustrates an apparatus according to the disclosure. The apparatus may include a sample support 200 that includes a sample holder 210, a sample stage 230, and a base 250. The sample stage 230 is disposed on the base 250. The sample holder 210 is disposed on the sample stage 230 and is configured to accept a diamond substrate.

As shown in FIGS. 2a-b , the base 250 may include a fluid container 255, which may be a water-block. The base 250 may further include a cover 252 that at least partially covers the fluid container 250. The cover 252 may include: molybdenum, tantalum, or a combination of both molybdenum and tantalum. As shown in FIG. 2b , the apparatus 200 may include a thermal separation 220 between the sample holder 210 and the sample stage 230. The apparatus 200 may also include water-cooled reactor wall 260 and choke 270.

FIG. 2c illustrates that the apparatus 200 may include multiple thermal interfaces between different structure layers. As shown in FIGS. 2a-c , the first thermal interface 282 is between the diamond substrate 280 and the sample holder 210. The second thermal interface 284 is between the sample holder 210 and the sample stage 230. The second thermal interface 284 may correspond to the thermal separation 220 in FIG. 2b . The third thermal interface 286 is between the sample stage 230 and the cover 252. The fourth thermal interface 288 is between the cover 252 and the fluid container 255.

The thermal interfaces may be controlled by separation of the corresponding components by a specified amount e.g. utilizing suitable spacer elements. For highest heat transfer the separation is eliminated through direct contact between the components. For example, thermal interfaces 282, 286 and 288 may be established through direct contact of the corresponding components while thermal interface 284 may be separated using 0.25 mm diameter tantalum wire spacers.

Here, thermal separation may be established through suitable spacers that can also be incorporated in the stage or sample holder element. Alternatively, the sample stage and holder may be manufactured into a single element. Each configuration presents a thermal assembly that may be tuned to requirements in the diamond growth process. In high microwave power applications, individual support elements may be merged and machined into a single unit to maintain temperature controlled support components.

FIG. 3a illustrates temperature changes over time according to the disclosure. The process 300 may include at least six repetitions 310, 320, 330, 340, 350, and 360. Each repetition may include a growth cycle and a cooling cycle. The growth cycle may have a longer time period than the cooling cycle.

For example, the temperature of the substrate may be controlled and recorded by a dual-color pyrometer that is capable of measuring temperatures>600° C. In FIG. 3a , the temperature profile is shown for a pulsed deposition run where growth and cooling have equal 5 minute periods repeated for 6 cycles. The final growth step 370 is adjusted to a temperature exceeding 1000° C. for about 2 minutes. It should be noted that the recorded curve is averaged during data acquisition. Further, the minimum temperature of 600° C. during cooling cycles represents the lower minimum of the pyrometer with the actual temperature less than 250° C.

FIG. 3b illustrates averaged and simulated temperature changes over time according to the disclosure. A detailed display of the growth pulse shown in FIG. 3b presents individual components that may be adjusted to achieve a continuous doping profile. Here, the ramp up (F) and ramp down (G) period may be determined by the configuration of the sample stage and CVD reactor. The temperature peak (A) may be adjusted through increased methane flow and also through adjustment of the microwave power/chamber pressure.

FIG. 4 illustrates P concentration over depth according to the disclosure. The SIMS profile 400 illustrates a phosphorus doped diamond film prepared by the pulsed growth technique. For example, the phosphorus incorporation for a doped diamond layer using the pulsed deposition mode may be evaluated by SIMS as shown in FIG. 4. The results indicate a significant doping concentration exceeding 1E18 cm-3. Increasing the phosphorus concentration during the growth pulse may achieve a higher dopant incorporation.

The table below shows some of the growth parameters for i-n structure

TABLE 1 Parameter Step 1 Step 2 (Step 3) × 7 Step 4 Hydrogen [sccm] 400 398 388 388 Methane [sccm] 0 2 2 2 TMP/Hydrogen 0 0 10 10 μ-wave [W] 2000 2000 2500 2500 Pressure [torr] 80 65 80 85 Pyrometer [° C.] 905 804 965 ~1000 Time [min] 15 360 5 5

For example, diamond deposition may be achieved through plasma enhanced chemical vapor deposition (PECVD) utilizing hydrogen (H2) as a carrier gas, methane (CH4) as a carbon source and a phosphorus source, here a 200 ppm trimethylphosphine/hydrogen (TMP/H2) gas mixture. In the pulsed deposition mode, hydrogen flow suitable for diamond growth is established, a plasma is ignited and chamber pressure and microwave power adjusted for diamond growth. With the diamond substrate at an elevated temperature, methane and the phosphorus source may be introduced at gas flow rates for diamond growth (less than 5% of the total gas flow for methane). As the carbon and phosphorus sources are introduced into the growth chamber, the doped deposition commences when the plasma is excited with microwave radiation which creates the reactive species for deposition and transfers energy to the substrate that results in a temperature rise. The duration of the growth pulse is accurately timed, and it is terminated by plasma shut-down.

A timed cooling period separates the deposition pulses where gas flow may optionally be established at similar flow rates. The repetitive growth pulses achieve significant phosphorus incorporation where the higher temperature growth pulses may increase the concentration of phosphorus incorporation to achieve n-type electrical properties. Variation of the gas flow rates, pressure, and plasma power may enable tuning the doping concentration and n-type doping characteristics.

Diamond may be synthesized by various techniques; high pressure-high temperature application, hot filament and plasma enhanced chemical vapor deposition (PECVD) where plasma enhanced growth processes are preferred in industrial operations that focus on high purity material with low defect densities. Diamond growth utilizing PECVD employs a gas mixture of hydrogen and methane where the methane flow rate may be up to several percent of the total gas flow rate. Dopants are similarly introduced, most commonly, through a gaseous source that may be diluted in hydrogen.

The disclosure provides an apparatus for deposition, the CVD reactor, which may be water-cooled to control the system temperature during growth. As the reactor walls are actively cooled adsorption of species like dopants can affect growth and doping processes. The reactor may include a water-cooled sample stage that holds the substrate. The experimental set-up is designed to allow heating of the substrate by plasma energy while maintaining all other reactor components at significantly lower temperatures.

With the substrate positioned in the plasma, its energy will result in heating, which may be further enhanced through a plasma focusing geometry enabled by the design of the substrate holder. This design eliminates the need of an additional substrate heater, which is often a source of impurities that reduce doping effectiveness. In this disclosure, a specially designed substrate holder that accepts single crystal diamond plates is mounted on a water-cooled sample stage. This configuration allows thermal controls where the diamond substrate may exhibit the greatest temperature increase because it is closest to the plasma and it can be thermally separated from actively cooled components. The materials of the sample holder exposed to the plasma are molybdenum, tantalum or similar and may be coated by diamond to reduce incorporation of impurities during plasma discharge.

The design of the thermal configuration provides a means to control the substrate temperature taking into account the microwave power, chamber pressure and gas flow rates. The stacked configuration of the sample stage/holder establishes thermal interfaces in FIG. 2c , which may be adjusted to achieve a temperature profile suitable for diamond growth. This protruding sample holder configuration allows control of the plasma geometry and a focusing of the plasma discharge occurs centered around the diamond substrate. With the accompanying increase in plasma density adjacent to the substrate, its temperature can be efficiently increased. As the surrounding components are actively cooled during growth, impurity incorporation is minimized and doping may be achieved through evolvement of adsorbed dopant species during film growth.

FIG. 5a illustrates a method according to a first aspect of the disclosure. The method 500 includes at least one of the following acts and additional acts may be added if needed. The method 500 may be implemented using a reactor such as a PECVD reactor. In act 520, a substrate is positioned in the PECVD reactor. The PECVD reactor may include robotic arms or other automatic component to position the substrate. The PECVD may include a base and a sample stage holder disposed on the base, where the sample stage holder comprises a sample holder.

In act 522, the PECVD reactor may use a controller to control temperature of the substrate by manipulating microwave power, chamber pressure, and gas flow rates of the PECVD reactor. The controller may be implemented using a hardware processor, a software program, or a combination of hardware and software.

In act 524, the PECVD reactor grows phosphorus doped diamond layer on the substrate using a pulsed deposition including a growth cycle and a cooling cycle. The growth cycle and cooling cycle may have an equal time duration as shown in FIG. 3a . Alternatively, the growth cycle and cooling cycle may have different durations.

In act 526, the PECVD reactor may iterate the growth cycle and the cooling cycle to establish the phosphorus doped diamond layer with a desired thickness. For example, the PECVD reactor may iterate at least four repetitions of growth and cooling cycles. The number of iterations may be adjusted by a controller.

FIG. 5b illustrates additional acts in the method of FIG. 5a according to the disclosure. In act 530, the PECVD reactor may position the substrate on a stage holder including a sample holder mounted on a base in the PECVD reactor. The PECVD reactor may cool the sample holder and the base by circulating fluid in a fluid container in the base. For example, the PECVD reactor may include a water container and use water circulation to cool the sample holder and the base.

In act 532, the PECVD reactor may establish one or more thermal interfaces in the stage holder by using a stacked configuration of the stage holder. The PECVD reactor may adjust the thermal interfaces to achieve a temperature profile suitable for diamond growth. For example, thermal insulation material may be added to one or more of the thermal interfaces when needed.

In act 534, the PECVD reactor may control a hydrogen gas flow at 400 sccm in the PECVD reactor to initiate the diamond growth process. The PECVD reactor may establish a pressure around 5 Torr for plasma ignition in the PECVD reactor at the same time.

In act 536, when a stable plasma discharge is formed, the PECVD reactor may adjust the microwave power and chamber pressure respectively at 60 to 80 Torr and 2000 to 2500 W. Depending on the desired growth rate and final dopant concentration in the substrate, the PECVD reactor may adjust the microwave power and chamber pressure accordingly.

In act 538, when a temperature of the substrate reaches a preset value, the PECVD reactor may introduce a 200 ppm trimethylphosphine (TMP)/H2 gas mixture and CH4 at flow rates of 1-10 sccm and 10-100 sccm, respectively.

FIG. 5c illustrates additional acts in the method of FIG. 5a according to the disclosure. In act 540, the PECVD reactor may increase growth temperature to a second preset value by adding methane. The PECVD reactor may stabilize the growth temperature at the second preset value during a preset growth period. The growth temperature may range between 900° C. and 1200° C. and the growth period may be about 5 minutes. The growth period may be longer or shorter to meet the desired growth rate.

In act 542, the PECVD reactor may terminate the growth cycle by reducing the microwave power and the chamber pressure to about 500 W and 20 Torr, respectively. In act 544, the PECVD reactor may shut off the microwave power after a preset ramp-down period. In act 546, the PECVD reactor may initiate the cooling cycle by using the process gas flow and simultaneously lowering the chamber pressure to about 1 Torr. The PECVD reactor may conclude the cooling cycle after about 5 minutes.

FIG. 6a illustrates an example method according to a second aspect of the disclosure. The method 600 includes at least one of the following acts. In act 620, a PECVD reactor is provided. The PECVD reactor includes: a base and a sample stage where the stage is disposed on the base and a holder disposed on the base.

In act 622, the thermal interface between the base and the sample stage holder may be adjusted. The thickness of the thermal interface may be adjusted by controlling the distance between different components of the base, stage and sample holder.

In act 624, a substrate is positioned in the sample holder in the PECVD reactor. The PECVD reactor may include a robotic arm or other mechanic components to position the substrate in the sample holder.

In act 626, a phosphorus doped diamond layer is grown on the substrate using a pulsed deposition. The PECVD reactor may use a controller to control growth parameters in the chamber during the pulsed deposition.

FIG. 6b illustrates additional acts in the method of FIG. 6a according to the disclosure. In act 630, the PECVD reactor may control a hydrogen gas flow at 400 sccm in the PECVD reactor; and establishes a pressure around 5 Torr for plasma ignition in the PECVD reactor. In act 632, when a stable plasma discharge is formed, the PECVD reactor may adjust the microwave power and chamber pressure respectively at about 2000 to 2500 W and 60 to 80 Torr. In act 634, when a temperature of the substrate reaches a preset value, the PECVD reactor may introduce a 200 ppm trimethylphosphine (TMP)/H2 gas mixture and CH4 at flow rates of 1-10 sccm and 10-100 sccm, respectively. In act 636, the PECVD reactor may increase growth temperature to a second preset value by adding methane. In act 638, the PECVD reactor may stabilize the growth temperature at the second preset value during a preset growth period.

FIG. 6c illustrates additional acts in the method of FIG. 6a according to the disclosure. In act 640, the PECVD reactor may terminate a growth cycle by reducing the microwave power and the chamber pressure to about 500 W and 20 Torr, respectively. In act 642, the PECVD reactor may shut off the microwave power after a preset ramp-down period. In act 644, the PECVD reactor may initiate a cooling cycle by using the process gas flow and simultaneously lowering the chamber pressure to about 1 Torr; and concluding the cooling cycle after about 5 minutes. In act 646, the PECVD reactor may iterate the growth cycle and the cooling cycle to establish the phosphorus doped diamond layer with a desired thickness.

Followings is an example for the growth process. In a water-cooled reactor, the hydrogen gas flow is controlled at about 400 sccm and a pressure suitable for plasma ignition (around 5 Torr) is established. When a stable plasma discharge is formed, the microwave power and chamber pressure is adjusted for diamond growth, here 2000 to 2500 W and 60 to 80 Torr, respectively.

As the temperature of the substrate in the hydrogen plasma reaches a pre-set value, around 800° C., the 200 ppm trimethylphosphine (TMP)/H2 gas mixture and CH4 is introduced at flow rates of 1-10 sccm and 10-100 sccm, respectively. With the addition of methane, a temperature increase is observed that may spike at a temperature>1000° C. and then stabilizes at the growth temperature established by pressure and microwave power. Utilizing plasma focusing in the sample holder configuration, the growth temperature may range between 900° C. and 1200° C. The growth period at this temperature may be timed for about 5 minutes. Termination of the growth cycle commences by reducing the microwave power and the chamber pressure to about 500 W and 20 Torr, respectively, in a ramp down process that is timed for about one minute after which the microwave power is shut off. This initiates the cooling cycle that is promoted by the process gas flow and simultaneously lowering of the chamber pressure to the minimum achievable by the process pump, here, 1 Torr. After about 5 minutes, this cooling cycle is concluded. The chamber pressure is then adjusted to about 5 Torr, methane and TMP/H2 flow shut down and a pure hydrogen plasma ignited which constitutes the beginning of a successive growth step.

Iterations of the growth and cooling cycle establish a phosphorus doped diamond layer with desired thickness. Higher doping concentrations may be achieved by increasing the supply of the dopant gas flow in the reactor, e.g. increased TMP/H2 flow rate, and increasing the microwave power/chamber pressure to obtain a higher substrate temperature.

FIG. 7a illustrates an outline of a sample holder according to the disclosure. The sample holder 700 includes a pocket 704 that accepts a diamond substrate 710. The sample holder 700 further includes flow channels 706 and 708 on different sides of the pocket 704. The sample holder 700 may have a diameter A of 10 mm and a height B of 3 mm. The pocket 704 has a pocket depth C of 1 mm. The radius of curvature for edge boundary is D of 1 mm. The flow channels 706 and 708 may have flow channel diameter of E of 0.25 mm and the pocket size of the pocket 704 is F of 3.5 mm.

FIG. 7b illustrates detailed view of the sample holder of FIG. 7a according to the disclosure. The distance between the flow channel top and the sample holder top is G, which is between 0.1 mm and 1 mm. The distance between the flow channel bottom and the diamond surface is H, which is between 0.1 mm and 1 mm. The radius of curvature for inner pocket is I, which is between 0.1 mm and 1 mm. The flow channel angle J is between 0.1° and 45°.

FIG. 7c illustrates a sample holder 700 a with elevated diamond substrate positioning according to the disclosure. The sample holder 700 a has a shallower pocket depth compared with the sample holder 700 shown in FIG. 7b . Here, the radius of curvature for edge boundary D is between 0.1 mm and 1 mm and the radius of curvature for inner pocket I is between 0.1 mm and 1 mm. Higher temperatures of the diamond substrate may be more readily achieved in a configuration where the diamond substrate is elevated on the sample holder 700 a. Plasma focusing occurs when a protruding sample holder geometry concentrates the plasma discharge at its outer boundary. The aspect ratio of holder height to its diameter defines the degree of concentration. This may be related to the growth temperature and doping efficiency. To control focusing effects at edged geometries, rounded corners may be used with precise radii of curvature to minimize material ablation.

The configurations in FIGS. 7a-c may affect diamond growth as they define the plasma discharge in the vicinity of the diamond surface and also the substrate temperature. This substrate accepting element defines how the substrate and its surface interact with the plasma. With a recessed sample holder geometry the substrate surface may be decoupled from the plasma in a controlled way which in turn allows controls of plasma focusing effects on the substrate surface at microscopic protrusions. In addition, gaseous species impinging on the diamond surface are controlled for a recessed holder geometry. A soft plasma ambient may be advantageous in the growth of ultra-smooth homoepitaxial diamond films. As diamond growth requires continuous supply of carbon to the substrate surface, stagnant gas pockets in the recessed holder are eliminated through incorporation of channels that establish a controlled flow of gaseous species across the substrate surface.

FIG. 8a illustrates flow channel distribution on a sample holder according to the disclosure. The sample holder 800 includes a pocket 805 in the center, which is configured to accept substrate. The sample holder 800 further includes eight flow channels 810, 812, 814, 816, 818, 820, 822, and 824. The separation angle K between channels 822 and 824 is about 45 degrees. In some embodiments, the number of flow channels may ranges between 2 to 10. However, the number of flow channels is not limited by examples in this disclosure.

FIG. 9a illustrates a sample stage with a single sample holder according to the disclosure. The example structure 830 includes a sample stage 832 and a single sample holder 800 disposed on the sample stage 832.

FIG. 9b illustrates a sample stage with multiple sample holders according to the disclosure. The example structure 830 includes three sample holders 834, 836, and 838 disposed on the sample stage 832. The number of sample holders are not limited by the disclosed examples in the disclosure.

FIG. 10 illustrates a reactor according to the disclosure. The reactor 900 may include a water-cooled support on an xyz movable stage implemented in a 5 kW CVD reactor. The reactor 900 may include a cover 910 that at least partially covers a fluid container 912. The fluid container 912 may be a water block. The cover 910 and fluid container 912 may be disposed in a choke 914, which is disposed on a support disk 920.

The reactor 900 may further include support 922 for the support disk 920. The support 922 may connect to a flange at the bottom of the reactor. The reactor further includes zero reducer flange 930 at least partially surrounding the support 922. The reactor 900 may also include a manipulator 940 around the bottom of the reactor 900.

Here, a novel growth process has been developed for phosphorus incorporation for n-type doping of diamond with (100) and related surface orientation. This growth mode can be obtained with a growth system that allows improved thermal management of the diamond substrate. With electronic grade n-type (100) diamond, discrete semiconductors for power electronics, radiation detectors and UV optoelectronics could be prepared more economically.

The disclosed pulsed deposition mode allows efficient doping of the (100) oriented diamond surface. This feature may be improved by utilization of a water-cooled growth reactor, sample stage and a sample holder configuration for controlled thermal management of the substrate. Compared to electronic grade n-type diamond prepared on (111) oriented diamond, the disclosed method requires a less elaborate processing resulting in lower cost and larger substrates.

The disclosed methods overcome the challenge for the growth of (100) phosphorus doped diamond its surface is polished at an angle, e.g. toward the (110) direction, up to tens of degrees. However, these off-axis plates require more elaborate preparation.

Although the invention has been described in considerable detail with reference to certain embodiments, one skilled in the art will appreciate that the present invention may be practiced by other than the described embodiments, which have been presented for purposes of illustration and not of limitation. Therefore, the scope of the appended claims should not be limited to the above description contained herein. 

What is claimed is:
 1. A method for manufacturing diamond electronic devices, the method comprising: positioning a single crystal substrate in a plasma enhanced chemical vapor deposition (PECVD) reactor; performing a deposition process, the deposition process comprising: i) establishing a plasma in the PECVD reactor; ii) stabilizing a temperature of the single crystal substrate at a first temperature between 900° C. and 1200° C. by controlling at least one of a microwave power of the plasma, a chamber pressure in the PECVD reactor, and a gas flow to the PECVD reactor; iii) epitaxially growing phosphorus doped diamond on the single crystal substrate at the first temperature for a growth period of greater than or equal to 2 minutes and less than 5 minutes; and iv) following the growth period, shutting down the plasma to cool the single crystal substrate below a second temperature for a cooling period, wherein the second temperature is 600° C.; and then v) iterating at least steps i) through iv) of the deposition process to deposit a phosphorus doped diamond layer on the single crystal substrate.
 2. The method of claim 1, wherein positioning a single crystal substrate in a plasma enhanced chemical vapor deposition (PECVD) reactor comprises: positioning the single crystal substrate on a stage holder comprising a sample holder mounted on a base in the PECVD reactor; and cooling the sample holder and the base by circulating fluid in a fluid container in the base.
 3. The method of claim 2, further comprising: establishing one or more thermal interfaces in the stage holder by using a stacked configuration of the stage holder; and adjusting the thermal interfaces to achieve a temperature profile suitable for diamond growth.
 4. The method of claim 1, wherein the deposition process further comprises: controlling a hydrogen gas flow at 400 sccm in the PECVD reactor; and wherein establishing the plasma in the PECVD reactor includes establishing a pressure of 5 Torr in the PECVD reactor.
 5. The method of claim 1, wherein epitaxially growing phosphorus doped diamond on the single crystal substrate comprises: when a stable plasma discharge is formed, adjusting the microwave power and chamber pressure respectively at 2000 to 2500 W and 60 to 80 Torr.
 6. The method of claim 1, wherein epitaxially growing phosphorus doped diamond on the single crystal substrate comprises: introducing a 200 ppm trimethylphosphine (TMP)/H2 gas mixture and CH4 at flow rates of 1-10 sccm and 10-100 sccm respectively, when a third temperature of the substrate reaches a preset value.
 7. The method of claim 1, wherein at least one growth period within the iterated deposition process is between 2 and 5 minutes.
 8. The method of claim 1, wherein epitaxially growing phosphorus doped diamond on the single crystal substrate comprises: terminating the growth period by reducing the microwave power and the chamber pressure to 500 W and 20 Torr, respectively; and shutting off the microwave power after a preset ramp-down period.
 9. The method of claim 1, wherein shutting down the plasma comprises: using the process gas flow and simultaneously lowering the chamber pressure to 1 Torr.
 10. A method for manufacturing diamond electronic devices, the method comprising: providing a plasma enhanced chemical vapor deposition (PECVD) reactor comprising: a base and a sample stage holder disposed on the base, wherein the sample stage holder comprises a sample holder; adjusting a thermal interface between the base and the sample stage holder; positioning a substrate in the sample holder in the PECVD reactor; and growing phosphorus doped diamond layer on the substrate using a deposition process comprising growth periods separated by cooling periods, wherein at least one growth period lasts for greater than or equal to 2 minutes and less than 5 minutes, and a plasma in the PECVD reactor is off during the cooling periods, wherein a temperature during at least one of the cooling periods is 600° C. or lower.
 11. The method of claim 10, wherein the base comprises a fluid container and a cover that at least partially covers the fluid container.
 12. The method of claim 10, wherein at least one of the growth periods last longer than at least one of the cooling periods.
 13. The method of claim 10, wherein growing phosphorus doped diamond layer on the substrate comprises: controlling a hydrogen gas flow at 400 sccm in the PECVD reactor; and establishing a pressure of 5 Torr for plasma ignition in the PECVD reactor.
 14. The method of claim 10, wherein growing phosphorus doped diamond layer on the substrate comprises: adjusting the microwave power and chamber pressure respectively at 2000 to 2500 W and 60 to 80 Torr after the plasma in the PECVD reactor has been ignited and has formed a stable discharge.
 15. The method of claim 10, wherein growing phosphorus doped diamond layer on the substrate comprises: when a temperature of the substrate occurring before a first growth period of the growth periods reaches a preset value, introducing a 200 ppm trimethylphosphine (TMP)/H2 gas mixture and CH4 at flow rates of 1-10 sccm and 10-100 sccm, respectively.
 16. The method of claim 10, wherein growing phosphorus doped diamond layer on the substrate comprises: increasing a growth temperature of the substrate to between 900° C. and 1200° C. by adding methane; and stabilizing the growth temperature during the at least one growth period.
 17. The method of claim 10, wherein growing phosphorus doped diamond layer on the substrate comprises: terminating at least one of the growth periods by reducing the microwave power and the chamber pressure to 500 W and 20 Torr, respectively; shutting off the microwave power after a preset ramp-down period; initiating at least one of the cooling periods by using the gas flow and simultaneously lowering the chamber pressure to 1 Torr; and concluding the at least one of the cooling periods after 5 minutes.
 18. The method of claim 17, further comprising: performing a number of growth periods and cooling periods sufficient to establish the phosphorus doped diamond layer with a preset thickness.
 19. The method of claim 10, wherein the substrate comprises a (100) oriented surface.
 20. A method for manufacturing diamond electronic devices, the method comprising: positioning a substrate in a plasma enhanced chemical vapor deposition (PECVD) reactor; performing a deposition process comprising: i) during a growth pulse of greater than 2 minutes and less than 5 minutes, growing phosphorus doped diamond on the substrate at a first temperature; ii) after the growth pulse, cooling the substrate to a second temperature that is less than the first temperature for a cooling period; and then iterating at least steps i) and ii) of the deposition process to form a phosphorus doped diamond layer on the substrate, wherein during iteration of the deposition process, a temperature profile of the growth pulse is adjusted to control a phosphorous concentration over a depth of the phosphorus doped diamond layer.
 21. The method of claim 20, wherein the method further comprises adjusting the temperature profile of the growth pulse so that the phosphorous dopant concentration exceeds 1E18 cm⁻³.
 22. The method of claim 20, wherein the second temperature is less than 600° C.
 23. The method of claim 22, wherein the second temperature is less than 250° C.
 24. The method of claim 1, wherein the second temperature is less than 250° C.
 25. The method of claim 1, wherein the single crystal substrate comprises a (100) oriented surface polished at an angle up to 10 degrees towards a (110) direction.
 26. The method of claim 1, wherein a chamber pressure in the PECVD reactor is equal to or greater than 1 Torr and less than 5 Torr between step iv) of the deposition process and step i) of a subsequent iteration of the deposition process. 